论文目录 | |
| Abstract | 第1-7页 |
| 摘要 | 第8-13页 |
| Chapter1 Introduction | 第13-30页 |
| 1.1 Silver nanowires | 第13-15页 |
| 1.1.1 AgNW optical properties | 第13-14页 |
| 1.1.2 Synthesis of AgNW | 第14-15页 |
| 1.2 Silver nanoparticles(AgNP) | 第15-18页 |
| 1.2.1 Silver nanoparticles(AgNP)optical properties | 第16-17页 |
| 1.2.2 Surface chemistry of silver nanoparticle(AgNP) | 第17页 |
| 1.2.3 Applications of silver nanoparticle(AgNP) | 第17页 |
| 1.2.4 PVP(Polyvinylpyrrolidone) | 第17-18页 |
| 1.3 Transparent electrode | 第18-20页 |
| 1.3.1 Metal nanostructured electrodes | 第19页 |
| 1.3.2 Metal thin films and grids | 第19-20页 |
| 1.3.3 Metal nanowire electrodes | 第20页 |
| 1.4 Metal oxide thin film | 第20-28页 |
| 1.4.1 Tungsten application | 第22-24页 |
| 1.4.2 Copper application | 第24-25页 |
| 1.4.3 Chromium application | 第25-27页 |
| 1.4.4 Manganese application | 第27-28页 |
| 1.5 Motivation of the present work | 第28-30页 |
| Chapter2 Experimental and Research methods | 第30-38页 |
| 2.1 Solution deposition methods | 第30页 |
| 2.2 Spin coating technique | 第30-32页 |
| 2.3 Polyol synthesis | 第32页 |
| 2.4 Characterization of transparent thin films based metal oxide/silver nanowires | 第32-38页 |
| 2.4.1 Scanning electron microscopy(SEM) | 第32-33页 |
| 2.4.2 X-ray diffraction | 第33-34页 |
| 2.4.3 X-ray Photoelectron Spectroscopy(XPS) | 第34-35页 |
| 2.4.4 Electrical transport properties(R-T)measurement | 第35页 |
| 2.4.5 Sheet resistance | 第35-36页 |
| 2.4.6 Transmittance and sheet resistance | 第36页 |
| 2.4.7 Flexibility of silver nanowire electrodes | 第36-38页 |
| Chapter3 Preparation and Characterization of AgNWs and comparison of transparent films of Ag NWs coated on PET and glass substrates | 第38-57页 |
| 3.1 Preparation of AgNWs | 第39-41页 |
| 3.1.1 Raw Materials | 第40-41页 |
| 3.1.2 Silver nanowire(AgNW)ink preparation and optimized process of transparent conductive films | 第41页 |
| 3.1.3 Characterization of(AgNWs)and transparent conductive thin films | 第41页 |
| 3.2 Morphology and aspect ratios of AgNWs | 第41-56页 |
| 3.2.1 The growth of AgNWs and nanostructures coarsening mechanism | 第49-50页 |
| 3.2.2 Properties of transparent conductive films | 第50-55页 |
| 3.2.3 Comparison of transmittance and sheet resistance of AgNW,ITO and other conductive thin films | 第55-56页 |
| 3.3 Summary | 第56-57页 |
| Chapter4 Study on high performance flexible MO_x(WO_3,CuO)/AgNWs based transparent conductive films | 第57-77页 |
| 4.1 Preparation of(AgNW)solutions and(AgNP)paste | 第58-62页 |
| 4.1.1 Raw Materials | 第59页 |
| 4.1.2 Preparation of WO_3,CuO and TiO_2 sol precursor solutions | 第59-60页 |
| 4.1.3 Electrode fabrication | 第60-61页 |
| 4.1.4 Electrode characterization | 第61-62页 |
| 4.2 Characterization of composite structure thin films with AgNW and AgNP | 第62-75页 |
| 4.2.1 The transparent conductive properties of composite thin films | 第64-68页 |
| 4.2.2 XPS analysis for WO_3/AgNW/WO_3/TiO_2/Epoxy/PET and WO_3/AgNP/WO_3/TiO_2/PET films | 第68-72页 |
| 4.2.3 XPS analysis for CuO/AgNW/CuO/TiO_2/Epoxy/PET and CuO/AgNP/CuO/TiO_2/PET films | 第72-75页 |
| 4.3 Summary | 第75-77页 |
| Chapter5 Preparation and characterization of flexible transparent films based on MOx(CrO_3,MnO_2)/AgNWs | 第77-96页 |
| 5.1 Fabrication of MNW and MNP electrodes | 第79-83页 |
| 5.1.1 Chemical and apparatus | 第80-81页 |
| 5.1.2 Preparation of (AgNW) solutions and (AgNP) paste | 第81-82页 |
| 5.1.3 Preparation of CrO_3,MnO_2 and TiO_2 sol precursor solutions | 第82页 |
| 5.1.4 Characterization of electrodes | 第82-83页 |
| 5.2 Characterization of composite structure thin films with AgNW and AgNP | 第83-95页 |
| 5.2.1 The transparent conductive properties of composite thin films | 第85-89页 |
| 5.2.2 XPS analysis for CrO_3/AgNW/CrO_3/TiO_2/Epoxy/PET and CrO_3/AgNP/CrO_3/TiO_2/PET films | 第89-92页 |
| 5.2.3 XPS analysis for MnO_2/AgNW/MnO_2/TiO_2/Epoxy/PET and MnO_2/AgNP/MnO_2/TiO_2/PET films | 第92-95页 |
| 5.3 Summary | 第95-96页 |
| Chapter6 Conclusions and Future work | 第96-98页 |
| 6.1 Conclusions | 第96-97页 |
| 6.2 Future work | 第97-98页 |
| Acknowledgements | 第98-99页 |
| References | 第99-107页 |
| Appendix Ⅰ List of Symbols and Abbreviations | 第107-108页 |
| Appendix Ⅱ Major Outcomes | 第108页 |
